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Futakawa, Masatoshi
Nihon Genshiryoku Gakkai-Shi, 47(8), p.530 - 535, 2005/08
no abstracts in English
Taniguchi, Naoki; Kawakami, Susumu; *
JNC TN8400 2001-025, 27 Pages, 2002/03
It is essential to understand the corrosion type of carbon steel under the repository conditions for the lifetime assessment of carbon steel overpack used for geological isolation of high-level radioactive waste. According to the previous study, carbon steel is hard to passivate in buffer material assuming a chemical condition range of groundwater in Japan. However, concrete support will be constructed around the overpack in the case of repository in the soft rock system and groundwater having a higher pH may infiltrate to buffer material. There is a possibility that the corrosion type of carbon steel will be influenced by the rise of the pH in groundwater. In this study, anodic polarization experiments were performed to understand the passivation condition of carbon steel in buffer material saturated with water contacted with concrete. An ordinary concrete and a low-alkalinity concrete were used in the experiment. The results of the experiments showed that the carbon steel can passivate under the condition that water having pH 13 infiltrate to the buffer material assuming present property of buffer material. If the low-alkalinity concrete is selected as the support material, passivation can not occur on carbon steel overpack. The effect of the factors of buffer material such as dry density and mixing ratio of sand on the passivation of carbon steel was also studied. The results of the study showed that the present property of buffer material is enough to prevent passivation of carbon steel.
Taniguchi, Naoki; ; Kawasaki, Manabu*; Masugata, Tsuyoshi*
JNC TN8400 2001-001, 56 Pages, 2000/12
It is necessary to clear the effects of corrosion products on the corrosion life time of carbon steel overpack for geological isolation of high-level radioactive waste(HLW). Especially, it is important to understand the effects of magnetite because magnetite as a simulated corrosion product is reported to accelerate the corrosion rate of carbon steel. In this study, corrosion tests to reproduce the acceleration of corrosion due to magnetite was performed and the mechanism of the acceleration was investigated to evaluate the effects of magnetite as a corrosion product. Based on the results of experiments, following conclusions are obtained ; (1)Magnetite powder accelerates the corrosion rate of carbon steel. The main reaction of corrosion under the presence of magnetite is the reduction of Fe(III) in magnetite to Fe(II), but the reaction of hydrogen generation is also accelerated. The contribution of hydrogen generation reaction was estimated to be about 30% in the total corrosion reaction based on the experimental result of immersion test under the presence of magnetite. (2)Actual corrosion products containing magnetite generated by the corrosion of carbon steel protect the metal from the propagation of corrosion. The corrosion depth of carbon steel overpack due to magnetite was estimated to be about 1 mm based on the results of experiments. Even if the effect of magnetite is taken into the assessment of corrosion lifetime of overpack, total corrosion depth in 1000 years is estimated to be 33 mm, which is smaller than the corrosion allowance of 40 mm described in the second progress report on research and development for the geological disposal of HLM/ in Japan. It was concluded that the effect of magnetite on the corrosion life time of carbon steel overpack is negligible.
; ;
JNC TN9400 2000-041, 29 Pages, 2000/03
Irradiation behavior and performance models were investigated in order to apply for nitride fuel options in feasibility study on fast breeder reactor and related recycle systems. (1)MechanicaI design of nitride fuel pin: The behaviors of fission gas release (increase of internal Pressure) and fuel-to-cladding chemical interaction (decrease of cladding thickness) are needed to evaluate cumulative damage fraction in case of fuel pin mechanical design. The behaviors of fission gas release and fuel-to-cladding chemical interaction were investigated from the past studies up to high burnuP, since the lower fission gas release in nitride fuel than in oxide fuel could contribute to reduce the plenum volume and result in the shortening of fuel Pin length. (2)Fuel pin smear density: The higher fuel smear density is preferred for the higher fissile density to improve the core characteristic. The behaviors of fuel pellet swelling were investigated from the past studies up to higher burnup, since the larger fuel pellet swelling in nitride fuel than in oxide fuel would restrict high burunp capability due to fuel-cladding mechanical interaction. (3)Compatibility of nitride fuel with high Temperature water: Compatibility of nitride fuel with high temperature water were investigated from the past studies to contribute water cooled fast breeder reactor options.
Shibata, Toshio*; *; *; Tsuru, Toru*; Inoue, Hiroyuki*
JNC TJ8400 2000-013, 38 Pages, 2000/02
None
Nagasaki, Shinya*
JNC TJ8400 2000-004, 32 Pages, 2000/02
Equilibrium and kinetics of sorption of NpO on illite were investigated at pH = 6 by using the differential pulse anodic stripping voltammetry method and the spectroscopic method, respectively. It was found that the sorption isotherm obtained was fitted better by the Langmuir-Freundlich type equation than by the Langmuir equation. The heterogeneity coefficient was 0.89 0.05 and the half width at half maximum (HWHM) of affinity spectrum was 0.19 log unit, indicating that the surfacc of illite used has a low degree of heterogeneity. The kinetic spectra indicated that the sorption of NpO occurs only at the outer surfacc. The mean HWHM of the kinetic spectra was 0.18 log unit. This also proves that the sorption kinetics of NpO on the illite used is controlled by the same heterogeneity of the sorption sites. From the dependence of mean rate constants on temperature, a mean apparent activation enthalpy and a mean apparent activation entropy were evaluated at 373 kJ/mol and - 69 7 J/Kmol, respectively. This value of enthalpy suggests that the sorption is not controlled by diffusion through the hydrodynamic film around the illite. Equilibrium and kinetics of sorption of NpO and Np(V) carbonate complexes (mainly NpOCO) on Na-montmorillonite were also examined by using same technique.
Tomari, Haruo*; *; Shimogori, Kazutoshi*; Wada, Ryutaro*; ; Taniguchi, Naoki
JNC TN8400 99-076, 100 Pages, 1999/10
Effects of bentonite clay, applied potential, pH, of solution and cathodic polarization time on hydrogen absorption into titanium, which is one of the candidate materials of overpack for high-level radioactive waste container, have been investigated in artificial underground water. Considering the result at various test time and assuming the hydrogen absorption is ruled by the paraboric law, the amount of hydrogen after 1000 years exposure calculated to about 17ppm, which will be absorbed at the applied potential of -0.51 vs. SHE corresponds to equilibrium potential of hydrogen. It seems the assumption of the parabolic law and the test period are proper, because the linear relations were obtained between the amount of absorbed hydrogen and the logarithm of the averaged cathodic current and between the slopes of the lines and a square root of the test time. Titanium seems to have a life over 1000 years in deep underground repository according to assumption that about 500ppm absorbed hydrogen is critical for hydrogen embrittlement of titanium.
Tsujikawa, Shigeo*; *; *; Tsuru, Toru*; Shibata, Toshio*; *
PNC TJ1560 97-001, 210 Pages, 1997/03
None
Seguchi, Tadao
Materiaru Raifu, 9(1), p.20 - 27, 1997/01
no abstracts in English
Kikuchi, Kenji; I.J.ODonnell*
Advances in Fracture Resistance in Materials, 3, p.73 - 81, 1996/06
no abstracts in English
Ito, Masayuki
Materiaru Raifu, 7(4), p.195 - 200, 1995/10
no abstracts in English
*; *; *; Yagi, Toshiaki; Seguchi, Tadao
Mitsubishi Densen Kogyo Jiho, (87), p.45 - 49, 1994/04
no abstracts in English
Yagi, Toshiaki; Seguchi, Tadao; *; *; *
Mitsubishi Densen Kogyo Jiho, (87), p.38 - 44, 1994/04
no abstracts in English
Kikuchi, Kenji; Kaji, Yoshiyuki;
Int. J. Press. Vessels Piping, 58, p.267 - 276, 1994/00
Times Cited Count:0 Percentile:0.02(Engineering, Multidisciplinary)no abstracts in English
Yagi, Toshiaki; Seguchi, Tadao; *; *; *
Mitsubishi Densen Kogyo Jiho, (84), p.11 - 17, 1992/10
no abstracts in English
; ; Inoue, K.*; Obata, Masamichi*; Ishikawa, Hirohisa; Sasaki, Noriaki
PNC TN8410 92-139, 105 Pages, 1992/05
None
; Ooka, Norikazu;
Genshiryoku Kogyo, 38(9), p.40 - 45, 1992/00
no abstracts in English
Kikuchi, Kenji; Kaji, Yoshiyuki
Engineering Fracture Mechanics, 40(4-5), p.749 - 755, 1991/00
Times Cited Count:0 Percentile:0.02(Mechanics)no abstracts in English